Abstract
The corrole–chromium(V)–nitrido moiety is introduced as a uniquely sensitive EPR spin probe. We describe a series of corrole-centered poly(amidoamine) (PAMAM) dendrimers and the selective incorporation of the chromium(V)–nitrido moiety. The chromium–corrole cores are reactive toward both neutral and charged reagents, and the accessibility of the dendrimer cores enables easy manipulation of the spin probe. The spin probe reveals a pronounced solvent dependence of the solution-phase structure of the dendrimers.
Originalsprog | Engelsk |
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Tidsskrift | Inorganic Chemistry |
Vol/bind | 50 |
Udgave nummer | 13 |
Sider (fra-til) | 5867–5869 |
Antal sider | 3 |
ISSN | 0020-1669 |
DOI | |
Status | Udgivet - 2011 |