Nanoparticles in a box: a concept to isolate, store and re-use colloidal surfactant-free precious metal nanoparticles

Sarah Neumann, Sarah Grotheer, Julia Tielke, Imke Schrader, Jonathan Quinson, Alessandro Zana, Mehtap Oezaslan, Matthias Arenz, Sebastian Kunz

Publikation: Bidrag til tidsskriftTidsskriftartikelForskningpeer review

38 Citationer (Scopus)

Abstract

A concept is introduced that allows for the isolation, storage and re-use of surfactant-free precious metal nanoparticles (NPs) of catalytic relevance (Pt and Ru). “Surfactant-free NPs” well-defined in size (1–2 nm) are prepared in alkaline ethylene glycol. After synthesis these NPs are stabilized by surface bound CO, formed during synthesis by solvent oxidation, and OH−, added to the reaction mixture. We present a protocol that allows switching reversibly the stabilization between a “CO-protected” and “OH−-protected state”. Most importantly, “OH−-protected” Pt and Ru NPs exhibit remarkable resistance against sintering. These NPs can be isolated as solids, stored and “put into boxes” to be shipped. Thereafter they can be redispersed without changes in particle size or loss in catalytic activity. These results are expected to be of scientific and industrial relevance, as a methodology is introduced to handle “surfactant-free” catalytic nanoparticles like a normal solid chemical
OriginalsprogEngelsk
TidsskriftJournal of Materials Chemistry A
Vol/bind5
Udgave nummer13
Sider (fra-til)6140-6145
Antal sider6
ISSN2050-7488
DOI
StatusUdgivet - 2017

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