Abstract
The primary and β-secondary kinetic isotope effects in the oxidation of secondary alcohols with dimethyl dioxirane were measured. The substantial primary and the absence of a β-secondary kinetic isotope effect support a concerted mechanism for the title reaction.
| Originalsprog | Engelsk |
|---|---|
| Tidsskrift | Tetrahedron Letters |
| Vol/bind | 42 |
| Udgave nummer | 22 |
| Sider (fra-til) | 3753-3756 |
| Antal sider | 4 |
| ISSN | 0040-4039 |
| DOI | |
| Status | Udgivet - 2001 |
| Udgivet eksternt | Ja |
Bibliografisk note
Funding Information:We thank the Greek Secretariat of Research and Technology (ΠENEΔ 1999 to I.S. and ΠENEΔ 1999 to M.O.) for financial support and for a research fellowship to Y.S.A. and N.S.H. Professor W. Adam is also acknowledged for valuable comments.
Finansiering
We thank the Greek Secretariat of Research and Technology (ΠENEΔ 1999 to I.S. and ΠENEΔ 1999 to M.O.) for financial support and for a research fellowship to Y.S.A. and N.S.H. Professor W. Adam is also acknowledged for valuable comments.
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