Sn(IV)-corroles reversibly bind carboxylates in the axial position

Helle Bak; Paolo Cavigli; Andrew Bond; Theis Brock-Nannestad; Michael Pittelkow; Elisabetta Iengo

doi:10.1142/S1088424623501080

Sn(IV)-corroles reversibly bind carboxylates in the axial position

Helle Bak, Paolo Cavigli, Andrew Bond, Theis Brock-Nannestad, Michael Pittelkow, Elisabetta Iengo^*

^*Corresponding author af dette arbejde

Kemisk Institut

Publikation: Bidrag til tidsskrift › Tidsskriftartikel › Forskning › peer review

Abstract

We present the synthesis of Sn(IV)-corrole complexes that bind to carboxylate moieties reversibly, via axial ligation. The systems have been predominantly characterized using 1H NMR spectroscopy, X-ray crystallography, and MALDI mass spectrometry. The dynamic nature of the Sn(IV)-O2CR bond has been studied in solution using 2D-NMR spectroscopy.

Originalsprog	Engelsk
Tidsskrift	Journal of Porphyrins and Phthalocyanines
Vol/bind	27
Udgave nummer	07n10
ISSN	1088-4246
DOI	https://doi.org/10.1142/S1088424623501080
Status	Udgivet - 2023

Bibliografisk note

Publisher Copyright:
© 2023 World Scientific Publishing Company.

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Citationsformater

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AU - Bak, Helle

AU - Cavigli, Paolo

AU - Bond, Andrew

AU - Brock-Nannestad, Theis

AU - Pittelkow, Michael

AU - Iengo, Elisabetta

PY - 2023

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AB - We present the synthesis of Sn(IV)-corrole complexes that bind to carboxylate moieties reversibly, via axial ligation. The systems have been predominantly characterized using 1H NMR spectroscopy, X-ray crystallography, and MALDI mass spectrometry. The dynamic nature of the Sn(IV)-O2CR bond has been studied in solution using 2D-NMR spectroscopy.

KW - carboxylate

KW - corrole

KW - exchange

KW - NMR

KW - Sn

KW - supramolecular

KW - x-ray

U2 - 10.1142/S1088424623501080

DO - 10.1142/S1088424623501080

M3 - Journal article

AN - SCOPUS:85165896670

SN - 1088-4246

VL - 27

JO - Journal of Porphyrins and Phthalocyanines

JF - Journal of Porphyrins and Phthalocyanines

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