Synthesis and mol-ecular structure of Cr(salen)(μ-N)RhCl(COD): The first example of a heterobimetallic nitride-bridged complex containing chromium

Johan Vibenholt; Magnus Magnussen; Christian Anthon; Jesper Bendix

doi:10.1107/S0108270110018238

Synthesis and mol-ecular structure of Cr(salen)(μ-N)RhCl(COD): The first example of a heterobimetallic nitride-bridged complex containing chromium

Johan Vibenholt, Magnus Magnussen, Christian Anthon, Jesper Bendix^*

^*Corresponding author af dette arbejde

Publikation: Bidrag til tidsskrift › Tidsskriftartikel › Forskning › peer review

3 Citationer (Scopus)

Abstract

Five-coordinate Cr(N)(salen) {salen is 2,2′-[ethane-1,2- diylbis(nitrilo-methyl-idyne)]diphenolate} reacts with [RhCl(COD)]₂ (COD is 1,5-cyclo-octa-diene) to yield the heterobimetallic nitride-bridged title compound, namely chlorido-2Cl-[2(η⁴)-1,5-cyclo-octa-diene] {2,2′-[ethane-1,2-diylbis(nitrilo-methyl-idyne)]diphenolato-1⁴ O,N,N′,O′} - nitrido-1:2² N:N-chromium(V)-rhodium(I), [CrRh(C₁₆H₁₄N₂O₂)ClN(C ₈H₁₂)]. The Cr - N bond of 1.5936 (14) Å is elongated by only 0.035 Å compared to the terminal Cr - N bond in the precursor. The nitride bridge is close to being linear [173.03 (9)°] and the Rh - N bond of 1.9594 (14) Å is very short for a monodentate nitro-gen-donor ligand, indicating significant π-acceptor character of the Cr ≡ N group.

Originalsprog	Engelsk
Tidsskrift	Acta Crystallographica Section C: Crystal Structure Communications
Vol/bind	66
Udgave nummer	7
Sider (fra-til)	m177-m179
Antal sider	3
ISSN	0108-2701
DOI	https://doi.org/10.1107/S0108270110018238
Status	Udgivet - 16 jul. 2010

Adgang til dokumentet

10.1107/S0108270110018238

Citationsformater

Synthesis and mol-ecular structure of Cr(salen)(μ-N)RhCl(COD) : The first example of a heterobimetallic nitride-bridged complex containing chromium. / Vibenholt, Johan; Magnussen, Magnus; Anthon, Christian ; Bendix, Jesper.

I: Acta Crystallographica Section C: Crystal Structure Communications, Bind 66, Nr. 7, 16.07.2010, s. m177-m179.

Publikation: Bidrag til tidsskrift › Tidsskriftartikel › Forskning › peer review

@article{43d94955f72e4706b42806e57af1a81e,

title = "Synthesis and mol-ecular structure of Cr(salen)(μ-N)RhCl(COD): The first example of a heterobimetallic nitride-bridged complex containing chromium",

abstract = "Five-coordinate Cr(N)(salen) {salen is 2,2′-[ethane-1,2- diylbis(nitrilo-methyl-idyne)]diphenolate} reacts with [RhCl(COD)]2 (COD is 1,5-cyclo-octa-diene) to yield the heterobimetallic nitride-bridged title compound, namely chlorido-2Cl-[2(η4)-1,5-cyclo-octa-diene] {2,2′-[ethane-1,2-diylbis(nitrilo-methyl-idyne)]diphenolato-14 O,N,N′,O′} - nitrido-1:22 N:N-chromium(V)-rhodium(I), [CrRh(C16H14N2O2)ClN(C 8H12)]. The Cr - N bond of 1.5936 (14) {\AA} is elongated by only 0.035 {\AA} compared to the terminal Cr - N bond in the precursor. The nitride bridge is close to being linear [173.03 (9)°] and the Rh - N bond of 1.9594 (14) {\AA} is very short for a monodentate nitro-gen-donor ligand, indicating significant π-acceptor character of the Cr ≡ N group.",

author = "Johan Vibenholt and Magnus Magnussen and Christian Anthon and Jesper Bendix",

year = "2010",

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doi = "10.1107/S0108270110018238",

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journal = "Acta crystallographica. Section C, Structural chemistry",

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TY - JOUR

T1 - Synthesis and mol-ecular structure of Cr(salen)(μ-N)RhCl(COD)

T2 - The first example of a heterobimetallic nitride-bridged complex containing chromium

AU - Vibenholt, Johan

AU - Magnussen, Magnus

AU - Anthon, Christian

AU - Bendix, Jesper

PY - 2010/7/16

Y1 - 2010/7/16

N2 - Five-coordinate Cr(N)(salen) {salen is 2,2′-[ethane-1,2- diylbis(nitrilo-methyl-idyne)]diphenolate} reacts with [RhCl(COD)]2 (COD is 1,5-cyclo-octa-diene) to yield the heterobimetallic nitride-bridged title compound, namely chlorido-2Cl-[2(η4)-1,5-cyclo-octa-diene] {2,2′-[ethane-1,2-diylbis(nitrilo-methyl-idyne)]diphenolato-14 O,N,N′,O′} - nitrido-1:22 N:N-chromium(V)-rhodium(I), [CrRh(C16H14N2O2)ClN(C 8H12)]. The Cr - N bond of 1.5936 (14) Å is elongated by only 0.035 Å compared to the terminal Cr - N bond in the precursor. The nitride bridge is close to being linear [173.03 (9)°] and the Rh - N bond of 1.9594 (14) Å is very short for a monodentate nitro-gen-donor ligand, indicating significant π-acceptor character of the Cr ≡ N group.

AB - Five-coordinate Cr(N)(salen) {salen is 2,2′-[ethane-1,2- diylbis(nitrilo-methyl-idyne)]diphenolate} reacts with [RhCl(COD)]2 (COD is 1,5-cyclo-octa-diene) to yield the heterobimetallic nitride-bridged title compound, namely chlorido-2Cl-[2(η4)-1,5-cyclo-octa-diene] {2,2′-[ethane-1,2-diylbis(nitrilo-methyl-idyne)]diphenolato-14 O,N,N′,O′} - nitrido-1:22 N:N-chromium(V)-rhodium(I), [CrRh(C16H14N2O2)ClN(C 8H12)]. The Cr - N bond of 1.5936 (14) Å is elongated by only 0.035 Å compared to the terminal Cr - N bond in the precursor. The nitride bridge is close to being linear [173.03 (9)°] and the Rh - N bond of 1.9594 (14) Å is very short for a monodentate nitro-gen-donor ligand, indicating significant π-acceptor character of the Cr ≡ N group.

U2 - 10.1107/S0108270110018238

DO - 10.1107/S0108270110018238

M3 - Journal article

AN - SCOPUS:77954519533

VL - 66

SP - m177-m179

JO - Acta crystallographica. Section C, Structural chemistry

JF - Acta crystallographica. Section C, Structural chemistry

SN - 2053-2296

IS - 7

ER -