Towards 31Mg-β-NMR resonance linewidths adequate for applications in magnesium chemistry

M. Stachura; R. M. L. McFadden; A. Chatzichristos; M. H. Dehn; A. Gottberg; Lars Bo Stegeager Hemmingsen; A. Jancso; V. L. Karner; R. F. Kiefl; Flemming Hofmann Larsen; J. Lassen; C. D. P. Levy; R. Li; W. A. MacFarlane; G. D. Morris; S. Pallada; M. R. Pearson; Daniel Mihaly Szunyogh; Peter Waaben Thulstrup; A. Voss

doi:10.1007/s10751-017-1408-8

Towards ³¹Mg-β-NMR resonance linewidths adequate for applications in magnesium chemistry

M. Stachura, R. M. L. McFadden, A. Chatzichristos, M. H. Dehn, A. Gottberg, Lars Bo Stegeager Hemmingsen, A. Jancso, V. L. Karner, R. F. Kiefl, Flemming Hofmann Larsen, J. Lassen, C. D. P. Levy, R. Li, W. A. MacFarlane, G. D. Morris, S. Pallada, M. R. Pearson, Daniel Mihaly Szunyogh, Peter Waaben Thulstrup, A. Voss

Publikation: Bidrag til tidsskrift › Tidsskriftartikel › Forskning › peer review

3 Citationer (Scopus)

Abstract

The span of most chemical shifts recorded in conventional 25Mg-NMR spectroscopy is ~ 100 ppm. Accordingly, linewidths of ~ 10 ppm or better are desirable to achieve adequate resolution for applications in chemistry. Here we present first high-field 31Mg- β-NMR measurements of 31Mg+ ions implanted into a MgO single crystal carried out at the ISAC facility at TRIUMF. The resonances recorded at 2.5 T and 3.5 T show strong linewidth dependency on the applied RF power, ranging from ~ 419 ppm for the highest RF power down to ~ 48 ppm for the lowest one.

Originalsprog	Engelsk
Artikelnummer	32
Tidsskrift	Hyperfine Interactions
Vol/bind	238
Udgave nummer	1
Antal sider	8
ISSN	0304-3843
DOI	https://doi.org/10.1007/s10751-017-1408-8
Status	Udgivet - 2017

Adgang til dokumentet

10.1007/s10751-017-1408-8

Citationsformater

Stachura, M., McFadden, R. M. L., Chatzichristos, A., Dehn, M. H., Gottberg, A., Hemmingsen, L. B. S., Jancso, A., Karner, V. L., Kiefl, R. F., Larsen, F. H., Lassen, J., Levy, C. D. P., Li, R., MacFarlane, W. A., Morris, G. D., Pallada, S., Pearson, M. R., Szunyogh, D. M., Thulstrup, P. W., & Voss, A. (2017). Towards ³¹Mg-β-NMR resonance linewidths adequate for applications in magnesium chemistry. Hyperfine Interactions, 238(1), [32]. https://doi.org/10.1007/s10751-017-1408-8

Towards ³¹Mg-β-NMR resonance linewidths adequate for applications in magnesium chemistry. / Stachura, M.; McFadden, R. M. L.; Chatzichristos, A.; Dehn, M. H.; Gottberg, A.; Hemmingsen, Lars Bo Stegeager; Jancso, A.; Karner, V. L.; Kiefl, R. F.; Larsen, Flemming Hofmann; Lassen, J.; Levy, C. D. P.; Li, R.; MacFarlane, W. A.; Morris, G. D.; Pallada, S.; Pearson, M. R.; Szunyogh, Daniel Mihaly; Thulstrup, Peter Waaben; Voss, A.

I: Hyperfine Interactions, Bind 238, Nr. 1, 32, 2017.

Publikation: Bidrag til tidsskrift › Tidsskriftartikel › Forskning › peer review

Stachura, M, McFadden, RML, Chatzichristos, A, Dehn, MH, Gottberg, A, Hemmingsen, LBS, Jancso, A, Karner, VL, Kiefl, RF, Larsen, FH, Lassen, J, Levy, CDP, Li, R, MacFarlane, WA, Morris, GD, Pallada, S, Pearson, MR, Szunyogh, DM, Thulstrup, PW & Voss, A 2017, 'Towards ³¹Mg-β-NMR resonance linewidths adequate for applications in magnesium chemistry', Hyperfine Interactions, bind 238, nr. 1, 32. https://doi.org/10.1007/s10751-017-1408-8

Stachura, M. ; McFadden, R. M. L. ; Chatzichristos, A. ; Dehn, M. H. ; Gottberg, A. ; Hemmingsen, Lars Bo Stegeager ; Jancso, A. ; Karner, V. L. ; Kiefl, R. F. ; Larsen, Flemming Hofmann ; Lassen, J. ; Levy, C. D. P. ; Li, R. ; MacFarlane, W. A. ; Morris, G. D. ; Pallada, S. ; Pearson, M. R. ; Szunyogh, Daniel Mihaly ; Thulstrup, Peter Waaben ; Voss, A. / Towards ³¹Mg-β-NMR resonance linewidths adequate for applications in magnesium chemistry. I: Hyperfine Interactions. 2017 ; Bind 238, Nr. 1.

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title = "Towards 31Mg-β-NMR resonance linewidths adequate for applications in magnesium chemistry",

abstract = "The span of most chemical shifts recorded in conventional 25Mg-NMR spectroscopy is ~ 100 ppm. Accordingly, linewidths of ~ 10 ppm or better are desirable to achieve adequate resolution for applications in chemistry. Here we present first high-field 31Mg- β-NMR measurements of 31Mg+ ions implanted into a MgO single crystal carried out at the ISAC facility at TRIUMF. The resonances recorded at 2.5 T and 3.5 T show strong linewidth dependency on the applied RF power, ranging from ~ 419 ppm for the highest RF power down to ~ 48 ppm for the lowest one.",

keywords = "beta-NMR, NMR, Magnesium, Metallobiochemistry, Linewidth",

author = "M. Stachura and McFadden, {R. M. L.} and A. Chatzichristos and Dehn, {M. H.} and A. Gottberg and Hemmingsen, {Lars Bo Stegeager} and A. Jancso and Karner, {V. L.} and Kiefl, {R. F.} and Larsen, {Flemming Hofmann} and J. Lassen and Levy, {C. D. P.} and R. Li and MacFarlane, {W. A.} and Morris, {G. D.} and S. Pallada and Pearson, {M. R.} and Szunyogh, {Daniel Mihaly} and Thulstrup, {Peter Waaben} and A. Voss",

year = "2017",

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T1 - Towards 31Mg-β-NMR resonance linewidths adequate for applications in magnesium chemistry

AU - Stachura, M.

AU - McFadden, R. M. L.

AU - Chatzichristos, A.

AU - Dehn, M. H.

AU - Gottberg, A.

AU - Hemmingsen, Lars Bo Stegeager

AU - Jancso, A.

AU - Karner, V. L.

AU - Kiefl, R. F.

AU - Larsen, Flemming Hofmann

AU - Lassen, J.

AU - Levy, C. D. P.

AU - Li, R.

AU - MacFarlane, W. A.

AU - Morris, G. D.

AU - Pallada, S.

AU - Pearson, M. R.

AU - Szunyogh, Daniel Mihaly

AU - Thulstrup, Peter Waaben

AU - Voss, A.

PY - 2017

Y1 - 2017

N2 - The span of most chemical shifts recorded in conventional 25Mg-NMR spectroscopy is ~ 100 ppm. Accordingly, linewidths of ~ 10 ppm or better are desirable to achieve adequate resolution for applications in chemistry. Here we present first high-field 31Mg- β-NMR measurements of 31Mg+ ions implanted into a MgO single crystal carried out at the ISAC facility at TRIUMF. The resonances recorded at 2.5 T and 3.5 T show strong linewidth dependency on the applied RF power, ranging from ~ 419 ppm for the highest RF power down to ~ 48 ppm for the lowest one.

AB - The span of most chemical shifts recorded in conventional 25Mg-NMR spectroscopy is ~ 100 ppm. Accordingly, linewidths of ~ 10 ppm or better are desirable to achieve adequate resolution for applications in chemistry. Here we present first high-field 31Mg- β-NMR measurements of 31Mg+ ions implanted into a MgO single crystal carried out at the ISAC facility at TRIUMF. The resonances recorded at 2.5 T and 3.5 T show strong linewidth dependency on the applied RF power, ranging from ~ 419 ppm for the highest RF power down to ~ 48 ppm for the lowest one.

KW - beta-NMR

KW - NMR

KW - Magnesium

KW - Metallobiochemistry

KW - Linewidth

U2 - 10.1007/s10751-017-1408-8

DO - 10.1007/s10751-017-1408-8

M3 - Journal article

VL - 238

JO - Hyperfine Interactions

JF - Hyperfine Interactions

SN - 0304-3843

IS - 1

M1 - 32

ER -