Lars Bo Stegeager Hemmingsen

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• 2024

  ¹⁹⁹Hg NMR Shielding and Chemical Shifts of 2-, 3- and 4-Coordinate Hg(II)-Thiolate Species

  Jessen, L. M., Sauer, S. P. A. & Hemmingsen, L. B. S., 2024, In: Inorganic Chemistry. 63, 50, p. 23614–23619 6 p.

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• As^III Selectively Induces a Disorder-to-Order Transition in the Metalloid Binding Region of the AfArsR Protein

  Tóth, A., Sajdik, K., Gyurcsik, B., Nafaee, Z. H., Wéber, E., Kele, Z., Christensen, N. J., Schell, J., Correia, J. G., Sigfridsson Clauss, K. G. V., Pittkowski, R. K., Thulstrup, P. W., Hemmingsen, L. & Jancsó, A., 2024, In: Journal of the American Chemical Society. 146, 25, p. 17009-17022 14 p.

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• Capturing Mercury-197m/g for Auger Electron Therapy and Cancer Theranostic with Sulfur-Containing Cyclen-Based Macrocycles

  Tosato, M., Randhawa, P., Asti, M., Hemmingsen, L. B. S., O'Shea, C. A., Thaveenrasingam, P., Sauer, S. P. A., Chen, S., Graiff, C., Menegazzo, I., Baron, M., Radchenko, V., Ramogida, C. F. & Di Marco, V., 2024, In: Inorganic Chemistry. 63, 30, p. 14241-14255 15 p.

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  2 Citations (Scopus)

• On the Geometry Dependence of the NMR Chemical Shift of Mercury in Thiolate Complexes: A Relativistic DFT Study

  Wu, H., Hemmingsen, L. B. S. & Sauer, S. P. A., 2024, In: Magnetic Resonance in Chemistry. 62, 9, p. 648-669 22 p.

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• S77C-ΔC7-CueR: a 199mHg PAC study of the protein metal site structure

  Balogh, R. K., Jancso, A., Gyurcsik, B., Schell, J., Correia, J. G., Thulstrup, P. W. & Hemmingsen, L., 2024, In: Interactions. 245, 7 p., 43.

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• 2023

  Calculation of electric field gradients in Cd(II) model complexes of the CueR protein metal site

  O'Shea, C. A., Fromsejer, R., Sauer, S. P. A., Mikkelsen, K. V. & Hemmingsen, L. B. S., 2023, In: Physical Chemistry Chemical Physics. 25, p. 12277-12283 7 p.

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  3 Citations (Scopus)

• Molecular rotational correlation times and nanoviscosity determined by ^111mCd perturbed angular correlation (PAC) of γ‐rays spectroscopy

  Fromsejer, R., Jensen, M. L., Zacate, M. O., Karner, V., Pecoraro, V. L. & Hemmingsen, L., 2023, In: Chemistry: A European Journal. 29, 9, 5 p., e202203084.

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• Near-surface dynamics of the ionic liquid EMIM-Ac above and below the glass transition

  Fujimoto, D., Karner, V. L., Dehn, M. H., Dunsiger, S. R., Hemmingsen, L., Kiefl, R. F., Mcfadden, R. M. L., Michal, C. A., Morris, G. D., Li, R., Pearson, M., Szunyogh, D., Thoeng, E., Ticknor, J. O., Macfarlane, W. A. & Stachura, M., 2023, In: Journal of Physics: Conference Series. 2462, 8 p., 012051.

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• Probing the Bioinorganic Chemistry of Cu(I) with 111Ag Perturbed Angular Correlation (PAC) Spectroscopy

  Karner, V., Jancso, A. & Hemmingsen, L., 2023, In: Inorganics. 11, 10, 13 p., 375.

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• Revisiting the hydrolysis of ampicillin catalyzed by Temoneira-1 β-lactamase, and the effect of Ni(II), Cd(II) and Hg(II)

  Nafaee, Z. H., Egyed, V., Jancsó, A., Tóth, A., Gerami, A. M., Dang, T. T., Heiniger-Schell, J., Hemmingsen, L., Hunyadi-Gulyás, É., Peintler, G. & Gyurcsik, B., 2023, In: Protein Science. 32, 12, 20 p., e4809.

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• 2022

  An Extremely Stable Interprotein Tetrahedral Hg(Cys)₄ Core Forms in the Zinc Hook Domain of Rad50 Protein at Physiological pH

  Luczkowski, M., Padjasek, M., Tran, J. B., Hemmingsen, L., Kerber, O., Habjanic, J., Freisinger, E. & Krezel, A., 2022, In: Chemistry: A European Journal. 28, 66, 13 p., e202202738.

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• Calculation of electric field gradients for CdI2 in the gas phase using BOMD simulations

  Fromsejer, R., Haas, H., Mikkelsen, K. & Hemmingsen, L., 16 Aug 2022, In: Chemical Physics Letters. 801, 4 p., 139704.

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• Magnesium(II)‐ATP Complexes in 1‐Ethyl‐3‐Methylimidazolium Acetate Solutions Characterized by ³¹Mg β‐Radiation‐Detected NMR Spectroscopy

  Mcfadden, R. M. L., Szunyogh, D., Bravo-frank, N., Chatzichristos, A., Dehn, M. H., Fujimoto, D., Jancsó, A., Johannsen, S., Kálomista, I., Karner, V. L., Kiefl, R. F., Larsen, F. H., Lassen, J., Levy, C. D. P., Li, R., Mckenzie, I., Mcphee, H., Morris, G. D., Pearson, M. R. & Sauer, S. P. A. & 5 others, Sigel, R. K. O., Thulstrup, P. W., Macfarlane, W. A., Hemmingsen, L. & Stachura, M., 26 Aug 2022, In: Angewandte Chemie International Edition. 61, 35, 8 p., e202207137.

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• Towards in vivo applications of¹¹¹ Ag perturbed angular correlation of γ-rays (PAC) spectroscopy

  Tosato, M., Asti, M., Di Marco, V., Jensen, M. L., Schell, J., Dang, T. T., Koster, U., Jensen, M. & Hemmingsen, L., 2022, In: Applied Radiation and Isotopes. 190, 8 p., 110508.

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• Tying Up a Loose End: On the Role of the C-Terminal CCHHRAG Fragment of the Metalloregulator CueR

  Balogh, R. K., Gyurcsik, B., Jensen, M., Thulstrup, P. W., Koester, U., Christensen, N. J., Jensen, M. L., Hunyadi-Gulyas, E., Hemmingsen, L. & Jancso, A., 2022, In: ChemBioChem. 23, 16, 9 p., 202200290.

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• 2021

  A reference compound for ^199mHg perturbed angular correlation of γ-rays spectroscopy

  Jancsó, A., Correia, J. G., Balogh, R. K., Schell, J., Jensen, M. L., Szunyogh, D., Thulstrup, P. W. & Hemmingsen, L., 21 Jun 2021, In: Nuclear Instruments and Methods in Physics Research, Section A: Accelerators, Spectrometers, Detectors and Associated Equipment. 1002, 165154.

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• Dynamics of nuclear recoil: QM-BOMD simulations of model systems following β-decay

  Fromsejer, R., Mikkelsen, K. V. & Hemmingsen, L., 2021, In: Physical Chemistry Chemical Physics. 23, 45, p. 25689–25698 10 p.

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  3 Citations (Scopus)

• Free molecule studies by perturbed γ-γ angular correlation: A new path to accurate nuclear quadrupole moments

  Haas, H., Röder, J., Correia, J. G., Schell, J., Fenta, A. S., Vianden, R., Larsen, E. M. H., Aggelund, P. A., Fromsejer, R., Hemmingsen, L. B. S., Sauer, S. P. A., Lupascu, D. C. & Amaral, V. S., 11 Mar 2021, In: Physical Review Letters. 126, 10-12, 6 p., 103001.

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• Perturbed angular correlation spectra due to rotating electric field gradients

  Zacate, M. O. & Hemmingsen, L. B. S., 2021, In: Hyperfine Interactions. 242, 13 p., 56.

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• 2020

  Flexibility of the CueR Metal Site Probed by Instantaneous Change of Element and Oxidation State from Ag^I to Cd^II

  Balogh, R. K., Gyurcsik, B., Jensen, M., Thulstrup, P. W., Köster, U., Christensen, N. J., Mørch, F. J., Jensen, M. L., Jancsó, A. & Hemmingsen, L., 2020, In: Chemistry: A European Journal. 26, 33, p. 7451-7457 7 p.

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  10 Citations (Scopus)

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• Probing the secondary structure of individual Aβ₄₀ amorphous aggregates and fibrils by AFM-IR spectroscopy

  Herzberg, M., Szunyogh, D., Thulstrup, P. W., Hassenkam, T. & Hemmingsen, L., 2020, In: ChemBioChem. p. 3521-3524 5 p.

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  14 Citations (Scopus)
• 2019

  C-terminal Cysteines of CueR Act as Auxiliary Metal Site Ligands upon Hg^II Binding—A Mechanism To Prevent Transcriptional Activation by Divalent Metal Ions?

  Balogh, R. K., Gyurcsik, B., Hunyadi-Gulyás, É., Schell, J., Thulstrup, P. W., Jancsó, A. & Hemmingsen, L. B. S., 2019, In: Chemistry - A European Journal. 25, 66, p. 15030–15035 6 p.

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  13 Citations (Scopus)

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• Dynamics of Liquid 1-Ethyl-3-Methylimidazolium Acetate Measured with Implanted-Ion ⁸Li β-NMR

  Fujimoto, D., McFadden, R. M. L., Dehn, M. H., Petel, Y., Chatzichristos, A., Hemmingsen, L. B. S., Karner, V. L., Kiefl, R. F., Levy, C. D. P., McKenzie, I., Michal, C. A., Morris, G. D., Pearson, M. R., Szunyogh, D. M., Ticknor, J. O., Stachura, M. & McFarlane, W. A., 2019, In: Chemistry of Materials. 31, 22, p. 9346-9353 7 p.

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  7 Citations (Scopus)

• Effects of Cu(II) on the aggregation of amyloid-β

  Weibull, M. G. M., Simonsen, S., Oksbjerg, C. R., Tiwari, M. K. & Hemmingsen, L., 2019, In: Journal of Biological Inorganic Chemistry. 24, p. 1197-1215 19 p.

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  39 Citations (Scopus)

• Hg²⁺ and Cd²⁺ binding of a bioinspired hexapeptide with two cysteine units constructed as a minimalistic metal ion sensing fluorescent probe

  Szekeres, L. I., Bálint, S., Galbács, G., Kálomista, I., Kiss, T., Larsen, F. H., Hemmingsen, L. & Jancsó, A., 2019, In: Dalton Transactions. 48, 23, p. 8327-8339

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• Rotational correlation times of proteins determined by ^111mCd PAC spectroscopy

  Fromsejer, R. & Hemmingsen, L. B. S., 2019, In: Hyperfine Interactions. 240, 1, 88.

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  2 Citations (Scopus)
• 2018

  Direct observation of Mg²⁺ complexes in ionic liquid solutions by ³¹Mg β-NMR spectroscopy

  Szunyogh, D., McFadden, R. M. L., Karner, V. L., Chatzichristos, A., Day Goodacre, T., Dehn, M. H., Formenti, L., Fujimoto, D., Gottberg, A., Kallenberg, E., Kálomista, I., Kiefl, R. F., Larsen, F. H., Lassen, J., Levy, C. D. P., Li, R., Macfarlane, W. A., McKenzie, I., Morris, G. D. & Pallada, S. & 6 others, Pearson, M. R., Sauer, S. P. A., Schaffer, P., Thulstrup, P. W., Hemmingsen, L. B. S. & Stachura, M., 2018, In: Dalton Transactions. 47, 41, p. 14431-14435 5 p.

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• Incorporation of second coordination sphere d-amino acids alters Cd(II) geometries in designed thiolate-rich proteins

  Ruckthong, L., Deb, A., Hemmingsen, L., Penner-Hahn, J. E. & Pecoraro, V. L., 1 Jan 2018, In: Journal of Biological Inorganic Chemistry. 23, 1, p. 123-135 13 p.

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  16 Citations (Scopus)
• 2017

  d-Cysteine Ligands Control Metal Geometries within De Novo Designed Three-Stranded Coiled Coils

  Ruckthong, L., Peacock, A. F. A., Pascoe, C. E., Hemmingsen, L. B. S., Stuckey, J. A. & Pecoraro, V. L., 2017, In: Chemistry - A European Journal. 23, 34, p. 8232-8243 12 p.

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  10 Citations (Scopus)

• Direct Observation of Nanosecond Water Exchange Dynamics at a Protein Metal Site

  Stachura, M. K., Chakraborty, S., Gottberg, A., Ruckthong, L., Pecoraro, V. L. & Hemmingsen, L. B. S., 2017, In: Journal of the American Chemical Society. 139, 1, p. 79-82 4 p.

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  15 Citations (Scopus)

• Nanosecond Dynamics at Protein Metal Sites: An Application of Perturbed Angular Correlation (PAC) of γ-Rays Spectroscopy

  Chakraborty, S., Pallada, S., Pedersen, J. T., Jancso, A., Correia, J. G. & Hemmingsen, L., 2017, In: Accounts of Chemical Research. 50, 9, p. 2225-2232 8 p.

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  7 Citations (Scopus)

• Quadrupole moments of Cd and Zn nuclei: When solid-state, molecular, atomic, and nuclear theory meet

  Haas, H., Sauer, S. P. A., Hemmingsen, L. B. S., Kellö, V. & Zhao, P. W., 2017, In: EPL. 117, 6, 6 p., 62001.

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• TDPAC and β-NMR applications in chemistry and biochemistry

  Jancso, A., Correia, J. G., Gottberg, A., Schell, J., Stachura, M., Szunyogh, D. M., Pallada, S., Lupascu, D. C., Kowalska, M. & Hemmingsen, L. B. S., 2017, In: Journal of Physics G: Nuclear and Particle Physics. 44, 6, 25 p., 064003.

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• The Pathogenic A2V Mutant Exhibits Distinct Aggregation Kinetics, Metal Site Structure, and Metal Exchange of the Cu²⁺-Aβ Complex

  Somavarapu, A. K., Shen, F., Teilum, K., Zhang, J., Mossin, S., Thulstrup, P. W., Bjerrum, M. J., Tiwari, M. K., Szunyogh, D., Søtofte, P. M., Kepp, K. P. & Hemmingsen, L., 2017, In: Chemistry - A European Journal. 23, 55, p. 13591-13595 5 p.

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  16 Citations (Scopus)

• Towards ³¹Mg-β-NMR resonance linewidths adequate for applications in magnesium chemistry

  Stachura, M., McFadden, R. M. L., Chatzichristos, A., Dehn, M. H., Gottberg, A., Hemmingsen, L. B. S., Jancso, A., Karner, V. L., Kiefl, R. F., Larsen, F. H., Lassen, J., Levy, C. D. P., Li, R., MacFarlane, W. A., Morris, G. D., Pallada, S., Pearson, M. R., Szunyogh, D. M., Thulstrup, P. W. & Voss, A., 2017, In: Hyperfine Interactions. 238, 1, 8 p., 32.

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  3 Citations (Scopus)
• 2016

  Amyloid-β and α-synuclein decrease the level of metal-catalyzed reactive oxygen species by radical scavenging and redox silencing

  Pedersen, J. T., Chen, S. W., Borg, C. B., Ness, S., Bahl, J. M., Heegard, N. H. H., Dobson, C. M., Hemmingsen, L. B. S., Cremades, N. & Teilum, K., 2016, In: Journal of the American Chemical Society. 138, 12, p. 3966-3969 4 p.

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• Versatile Ion-polarized Techniques On-line (VITO) experiment at ISOLDE-CERN

  Stachura, M. K., Gottberg, A., Johnston, K., Bissell, M. L., Ruiz, R. F. G., Martins Correia, J., Granadeiro Costa, A. R., Dehn, M., Deicher, M., Fenta, A. S., Hemmingsen, L. B. S., Molholt, T. E., Munch, M., Neyens, G., Pallada, S., Silva, M. R. & Zakoucky, D., 2016, In: Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms. 376, p. 369-373 5 p.

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  6 Citations (Scopus)
• 2015

  Aggregation prone amyloid-β⋅Cu^II Species formed on the millisecond timescale at mildly acidic conditions

  Pedersen, J. T., Borg, C. B., Michaels, T. C. T., Knowles, T. P. J., Faller, P., Teilum, K. & Hemmingsen, L. B. S., 2015, In: ChemBioChem. 16, 9, p. 1293-1297 5 p.

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  26 Citations (Scopus)

• Metal ion mediated transition from random coil to β-sheet and aggregation of Bri2-23, a natural inhibitor of Aβ aggregation

  Luczkowski, M., De Ricco, R., Stachura, M. K., Potocki, S., Hemmingsen, L. B. S. & Valensin, D., 2015, In: Metallomics. 7, 3, p. 478-490 13 p.

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• Perspectives for the VITO beam line at ISOLDE, CERN

  Garcia Ruiz, R. F., Bissel, M. L., Gottberg, A., Stachura, M. K., Hemmingsen, L. B. S., Neyens, G. & Severijns, N., 2015, Proceedings, 15th International Symposium on Capture Gamma-Ray Spectroscopy and Related Topics (CGS15): Dresden, Germany, August 25-29, 2014. Schwengner, R. & Zuber, K. (eds.). EDP Sciences, 6 p. 07004. (E P J Web of Conferences, Vol. 93).

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• Specificity of the metalloregulator CueR for monovalent metal ions: possible functional role of a coordinated thiol?

  Szunyogh, D., Szokolai, H., Thulstrup, P. W., Larsen, F. H., Gyurcsik, B., Christensen, N. J., Stachura, M. K., Hemmingsen, L. B. S. & Jancsó, A., 2015, In: Angewandte Chemie International Edition. 54, 52, p. 15756-15761 6 p.

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  17 Citations (Scopus)

• Toward applications of β-NMR spectroscopy in chemistry and biochemistry

  Stachura, M. K., Gottberg, A., Kowalska, M., Johnston, K. & Hemmingsen, L. B. S., 2015, In: Nuclear Physics News. 25, 2, p. 25-29 5 p.

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  2 Citations (Scopus)

• Variable primary coordination environments of Cd(ɪɪ) binding to three helix bundles provide a pathway for rapid metal exchange

  Tebo, A. G., Hemmingsen, L. B. S. & Pecoraro, V. L., 2015, In: Metallomics. 7, 12, p. 1555-1561 7 p.

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  15 Citations (Scopus)

• Zn^II and Hg^II binding to a designed peptide that accommodates different coordination geometries

  Szunyogh, D., Gyurcsik, B., Larsen, F. H., Stachura, M., Thulstrup, P. W., Hemmingsen, L. B. S. & Jancsó, A., 2015, In: Dalton Transactions (Print Edition). 44, p. 12576–12588 13 p.

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• 2014

  Billion-fold enhancement in sensitivity of nuclear magnetic resonance spectroscopy for magnesium ions in solution

  Gottberg, A., Stachura, M. K., Kowalska, M., Bissell, M. L., Arcisauskaité, V., Blaum, K., Helmke, A., Johnston, K., Kreim, K., Larsen, F. H., Neugart, R., Neyens, G., Ruiz, R. F. G., Szunyogh, D., Thulstrup, P. W., Yordanov, D. T. & Hemmingsen, L. B. S., 2014, In: ChemPhysChem. 15, 18, p. 3929–3932 4 p.

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  16 Citations (Scopus)

• Binding of Cu²⁺ to the islet amyloid polypeptide (IAPP)

  Andersen-Usaj, J., Bonde, A. C., Pihl, J., Thomsen, M.-L. F., Shavit, M., Pedersen, J. T., Teilum, K., Thulstrup, P. W. & Hemmingsen, L. B. S., 2014, In: Journal of Biological Inorganic Chemistry. 19, suppl. 2, p. S812 1 p., P 101.

  Research output: Contribution to journal › Conference abstract in journal › Research › peer-review

• Islet amyloid polypeptide (IAPP)-Structural effects of Zn²⁺

  Shavit, M., Bonde, A. C., Pihl, J., Thomsen, M.-L. F., Pedersen, J. T., Andersen-Usaj, J., Teilum, K., Hemmingsen, L. B. S. & Thulstrup, P. W., 2014, In: Journal of Biological Inorganic Chemistry. 19, Suppl. 2, p. S813 1 p., P 102.

  Research output: Contribution to journal › Conference abstract in journal › Research › peer-review

  38 Citations (Scopus)

• pH dependence of amyloid-β-Cu(II) binding and oligomerization kinetics

  Pedersen, J. T., Borg, C. B., Teilum, K. & Hemmingsen, L. B. S., 2014, In: Journal of Biological Inorganic Chemistry. 19, Suppl 2, p. S755 1 p.

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• 2013

  Controlling self-assembly of a peptide-based material via metal-ion induced registry shift

  Anzini, P., Xu, C., Hughes, S., Magnotti, E., Jiang, T., Hemmingsen, L. B. S., Demeler, B. & Conticello, V. P., 2013, In: Journal of the American Chemical Society. 135, 28, p. 10278-10281 4 p.

  Research output: Contribution to journal › Journal article › Research › peer-review
  53 Citations (Scopus)

• Metal ion interaction of an oligopeptide fragment representing the regulatory metal binding site of a CueR protein

  Jancsó, A., Szokolai, H., Roszahegyi, L., Szunyogh, D., Hemmingsen, L. B. S., Thulstrup, P. W. & Larsen, F. H., 2013. 1 p.

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