TY - JOUR
T1 - Comparison of microemulsion electrokinetic chromatography and solvent-modified micellar electrokinetic chromatography
AU - Hansen, Steen Honoré
AU - Gabel-Jensen, Charlotte
AU - Pedersen-Bjergaard, Stig
PY - 2001/10/22
Y1 - 2001/10/22
N2 - Microemulsion electrokinetic chromatography (MEEKC) was investigated with the goal of elucidating the influence exerted by the amount of lipophilic organic phase and the amount of co-surfactant on the migration of a number of neutral test solutes. Furthermore, MEEKC was compared to solvent-modified micellar electrokinetic chromatography (MEKC). The organic solvents methanol, ethanol, 1-propanol, 1-butanol, acetonitrile, tetrahydrofuran, and 2-ethoxyethanol serving as co-surfactants in MEEKC were used in similar concentrations in MEKC systems in order to compare the selectivity and separation efficiency of the two kinds of system. The solvent-modified MEKC technique proved to be very similar to MEEKC in performance with respect to both separation selectivity and efficiency of separation.
AB - Microemulsion electrokinetic chromatography (MEEKC) was investigated with the goal of elucidating the influence exerted by the amount of lipophilic organic phase and the amount of co-surfactant on the migration of a number of neutral test solutes. Furthermore, MEEKC was compared to solvent-modified micellar electrokinetic chromatography (MEKC). The organic solvents methanol, ethanol, 1-propanol, 1-butanol, acetonitrile, tetrahydrofuran, and 2-ethoxyethanol serving as co-surfactants in MEEKC were used in similar concentrations in MEKC systems in order to compare the selectivity and separation efficiency of the two kinds of system. The solvent-modified MEKC technique proved to be very similar to MEEKC in performance with respect to both separation selectivity and efficiency of separation.
KW - MEEKC
KW - MEKC
KW - Micellar electrokinetic chromatography
KW - Microemulsion electrokinetic chromatography
KW - Pseudo-stationary phases
UR - http://www.scopus.com/inward/record.url?scp=0034795174&partnerID=8YFLogxK
U2 - 10.1002/1615-9314(20010801)24:8<643::AID-JSSC643>3.0.CO;2-U
DO - 10.1002/1615-9314(20010801)24:8<643::AID-JSSC643>3.0.CO;2-U
M3 - Journal article
AN - SCOPUS:0034795174
SN - 1615-9306
VL - 24
SP - 643
EP - 650
JO - Journal of Separation Science
JF - Journal of Separation Science
IS - 8
ER -