Correction to “Atmospheric Chemistry of CH3OCF2CHF2”

Eva R. Kjærgaard; Emil Vogt; Kristian H. Møller; Ole John Nielsen; Henrik G. Kjaergaard

doi:10.1021/acs.jpca.3c03255

Correction to “Atmospheric Chemistry of CH3OCF2CHF2”

Eva R. Kjærgaard, Emil Vogt, Kristian H. Møller, Ole John Nielsen, Henrik G. Kjaergaard

Research output: Contribution to journal › Comment/debate › Research › peer-review

Abstract

We are updating our earlier paper in The Journal of Physical Chemistry A to correct an error in the stated reactant pressure.1 Due to a minor leak in the sample holder, the stated pressures of the reactant, CH₃OCF₂CHF₂, added to the reaction chamber are overestimated. This does not affect the published rate coefficients, as they were determined using the relative rate method, nor the lifetime determined. However, this does affect the results published regarding the branching ratios for H-abstraction by Cl, the product formation ratios and yields, the absolute IR spectra and the determined global warming potentials. The pressures of other species in the experiments were unaffected by this and are correctly stated in the original publication.

Original language	English
Journal	Journal of Physical Chemistry A
Volume	127
Issue number	25
Pages (from-to)	5520–5521
Number of pages	2
ISSN	1089-5639
DOIs	https://doi.org/10.1021/acs.jpca.3c03255
Publication status	Published - 2023

Bibliographical note

Publisher Copyright:
© 2023 American Chemical Society.

Access to Document

10.1021/acs.jpca.3c03255

Cite this

@article{3a5392407fb6437d93b748ac5c279ef5,

title = "Correction to “Atmospheric Chemistry of CH3OCF2CHF2”",

abstract = "We are updating our earlier paper in The Journal of Physical Chemistry A to correct an error in the stated reactant pressure.1 Due to a minor leak in the sample holder, the stated pressures of the reactant, CH3OCF2CHF2, added to the reaction chamber are overestimated. This does not affect the published rate coefficients, as they were determined using the relative rate method, nor the lifetime determined. However, this does affect the results published regarding the branching ratios for H-abstraction by Cl, the product formation ratios and yields, the absolute IR spectra and the determined global warming potentials. The pressures of other species in the experiments were unaffected by this and are correctly stated in the original publication.",

author = "Kj{\ae}rgaard, {Eva R.} and Emil Vogt and M{\o}ller, {Kristian H.} and Nielsen, {Ole John} and Kjaergaard, {Henrik G.}",

note = "Publisher Copyright: {\textcopyright} 2023 American Chemical Society.",

year = "2023",

doi = "10.1021/acs.jpca.3c03255",

language = "English",

volume = "127",

pages = "5520–5521",

journal = "Journal of Physical Chemistry Part A: Molecules, Spectroscopy, Kinetics, Environment and General Theory",

issn = "1089-5639",

publisher = "American Chemical Society",

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TY - JOUR

T1 - Correction to “Atmospheric Chemistry of CH3OCF2CHF2”

AU - Kjærgaard, Eva R.

AU - Vogt, Emil

AU - Møller, Kristian H.

AU - Nielsen, Ole John

AU - Kjaergaard, Henrik G.

PY - 2023

Y1 - 2023

N2 - We are updating our earlier paper in The Journal of Physical Chemistry A to correct an error in the stated reactant pressure.1 Due to a minor leak in the sample holder, the stated pressures of the reactant, CH3OCF2CHF2, added to the reaction chamber are overestimated. This does not affect the published rate coefficients, as they were determined using the relative rate method, nor the lifetime determined. However, this does affect the results published regarding the branching ratios for H-abstraction by Cl, the product formation ratios and yields, the absolute IR spectra and the determined global warming potentials. The pressures of other species in the experiments were unaffected by this and are correctly stated in the original publication.

AB - We are updating our earlier paper in The Journal of Physical Chemistry A to correct an error in the stated reactant pressure.1 Due to a minor leak in the sample holder, the stated pressures of the reactant, CH3OCF2CHF2, added to the reaction chamber are overestimated. This does not affect the published rate coefficients, as they were determined using the relative rate method, nor the lifetime determined. However, this does affect the results published regarding the branching ratios for H-abstraction by Cl, the product formation ratios and yields, the absolute IR spectra and the determined global warming potentials. The pressures of other species in the experiments were unaffected by this and are correctly stated in the original publication.

U2 - 10.1021/acs.jpca.3c03255

DO - 10.1021/acs.jpca.3c03255

M3 - Comment/debate

C2 - 37315189

AN - SCOPUS:85164123962

VL - 127

SP - 5520

EP - 5521

JO - Journal of Physical Chemistry Part A: Molecules, Spectroscopy, Kinetics, Environment and General Theory

JF - Journal of Physical Chemistry Part A: Molecules, Spectroscopy, Kinetics, Environment and General Theory

SN - 1089-5639

IS - 25

ER -