Effects of intramolecular motion on the magnetic resonance of anisotropic liquids: the equivalence of kinetic and equilibrium statistical mechanical approaches

E. E. Burnell; C. A. de Lange; O. G. Mouritsen

doi:10.1016/0022-2364(82)90048-8

Effects of intramolecular motion on the magnetic resonance of anisotropic liquids: the equivalence of kinetic and equilibrium statistical mechanical approaches

E. E. Burnell^*, C. A. de Lange, O. G. Mouritsen

^*Corresponding author for this work

Research output: Contribution to journal › Journal article › Research › peer-review

26 Citations (Scopus)

Abstract

The effects of internal molecular motions on the average orientation of molecules in anisotropic fluids may be described by kinetics as well as equilibrium statistical mechanics. The magnetic resonance of partially oriented molecules is equally well described by models based on either of the two equivalent approaches. However, a model based on kinetic parameters is more readily related to accessible experimental data.

Original language	English
Journal	Journal of Magnetic Resonance (1969)
Volume	50
Issue number	2
Pages (from-to)	188-196
Number of pages	9
ISSN	0022-2364
DOIs	https://doi.org/10.1016/0022-2364(82)90048-8
Publication status	Published - 1982
Externally published	Yes

Access to Document

10.1016/0022-2364(82)90048-8

Cite this

Effects of intramolecular motion on the magnetic resonance of anisotropic liquids : the equivalence of kinetic and equilibrium statistical mechanical approaches. / Burnell, E. E.; de Lange, C. A.; Mouritsen, O. G.

In: Journal of Magnetic Resonance (1969), Vol. 50, No. 2, 1982, p. 188-196.

Research output: Contribution to journal › Journal article › Research › peer-review

@article{7f61816258d547f6bbd5d8497be614e0,

title = "Effects of intramolecular motion on the magnetic resonance of anisotropic liquids: the equivalence of kinetic and equilibrium statistical mechanical approaches",

abstract = "The effects of internal molecular motions on the average orientation of molecules in anisotropic fluids may be described by kinetics as well as equilibrium statistical mechanics. The magnetic resonance of partially oriented molecules is equally well described by models based on either of the two equivalent approaches. However, a model based on kinetic parameters is more readily related to accessible experimental data.",

author = "Burnell, {E. E.} and {de Lange}, {C. A.} and Mouritsen, {O. G.}",

year = "1982",

doi = "10.1016/0022-2364(82)90048-8",

language = "English",

volume = "50",

pages = "188--196",

journal = "Journal of Magnetic Resonance (1969)",

issn = "0022-2364",

publisher = "Academic Press",

number = "2",

}

TY - JOUR

T1 - Effects of intramolecular motion on the magnetic resonance of anisotropic liquids

T2 - the equivalence of kinetic and equilibrium statistical mechanical approaches

AU - Burnell, E. E.

AU - de Lange, C. A.

AU - Mouritsen, O. G.

PY - 1982

Y1 - 1982

N2 - The effects of internal molecular motions on the average orientation of molecules in anisotropic fluids may be described by kinetics as well as equilibrium statistical mechanics. The magnetic resonance of partially oriented molecules is equally well described by models based on either of the two equivalent approaches. However, a model based on kinetic parameters is more readily related to accessible experimental data.

AB - The effects of internal molecular motions on the average orientation of molecules in anisotropic fluids may be described by kinetics as well as equilibrium statistical mechanics. The magnetic resonance of partially oriented molecules is equally well described by models based on either of the two equivalent approaches. However, a model based on kinetic parameters is more readily related to accessible experimental data.

U2 - 10.1016/0022-2364(82)90048-8

DO - 10.1016/0022-2364(82)90048-8

M3 - Journal article

AN - SCOPUS:0542428201

VL - 50

SP - 188

EP - 196

JO - Journal of Magnetic Resonance (1969)

JF - Journal of Magnetic Resonance (1969)

SN - 0022-2364

IS - 2

ER -