Extended tetrathiafulvalene with a pentaleno[1,2-b:4,5-b′]difluorene core - a donor-acceptor multi-redox system

Jeppe Granhøj; Viktor Bliksted Roug Pedersen; Kurt V. Mikkelsen; Mogens Brøndsted Nielsen

doi:10.1039/d4ob01755b

Extended tetrathiafulvalene with a pentaleno[1,2-b:4,5-b′]difluorene core - a donor-acceptor multi-redox system

Jeppe Granhøj, Viktor Bliksted Roug Pedersen, Kurt V. Mikkelsen, Mogens Brøndsted Nielsen^*

^*Corresponding author for this work

Department of Chemistry

Research output: Contribution to journal › Journal article › Research › peer-review

Abstract

A novel extended tetrathiafulvalene was prepared by introducing the large pentaleno[1,2-b:4,5-b′]difluorene as a central polycyclic aromatic hydrocarbon moiety. This compound behaved as a multi-redox system that could take reversibly six redox states (−1, 0, +1, +2, +3, +4). The compound exhibited strong absorptions in the visible region with an end-absorption almost reaching to 700 nm.

Original language	English
Journal	Organic and Biomolecular Chemistry
Volume	22
Issue number	47
Pages (from-to)	9259–9265
Number of pages	7
ISSN	1477-0520
DOIs	https://doi.org/10.1039/d4ob01755b
Publication status	Published - 2024

Bibliographical note

Funding Information:
The Novo Nordisk Foundation is acknowledged for financially supporting this work (grant #NNF20OC0061574).

Publisher Copyright:
© 2024 The Royal Society of Chemistry.

Access to Document

10.1039/d4ob01755b

Cite this

Extended tetrathiafulvalene with a pentaleno[1,2-b:4,5-b′]difluorene core - a donor-acceptor multi-redox system. / Granhøj, Jeppe; Pedersen, Viktor Bliksted Roug ; Mikkelsen, Kurt V.; Nielsen, Mogens Brøndsted.

In: Organic and Biomolecular Chemistry, Vol. 22, No. 47, 2024, p. 9259–9265 .

Research output: Contribution to journal › Journal article › Research › peer-review

@article{710214fa39104e36a0fb3183b4420d48,

title = "Extended tetrathiafulvalene with a pentaleno[1,2-b:4,5-b′]difluorene core - a donor-acceptor multi-redox system",

abstract = "A novel extended tetrathiafulvalene was prepared by introducing the large pentaleno[1,2-b:4,5-b′]difluorene as a central polycyclic aromatic hydrocarbon moiety. This compound behaved as a multi-redox system that could take reversibly six redox states (−1, 0, +1, +2, +3, +4). The compound exhibited strong absorptions in the visible region with an end-absorption almost reaching to 700 nm.",

author = "Jeppe Granh{\o}j and Pedersen, {Viktor Bliksted Roug} and Mikkelsen, {Kurt V.} and Nielsen, {Mogens Br{\o}ndsted}",

note = "Funding Information: The Novo Nordisk Foundation is acknowledged for financially supporting this work (grant #NNF20OC0061574). Publisher Copyright: {\textcopyright} 2024 The Royal Society of Chemistry.",

year = "2024",

doi = "10.1039/d4ob01755b",

language = "English",

volume = "22",

pages = "9259–9265 ",

journal = "Organic & Biomolecular Chemistry",

issn = "1470-4358",

publisher = "Royal Society of Chemistry",

number = "47",

}

TY - JOUR

T1 - Extended tetrathiafulvalene with a pentaleno[1,2-b:4,5-b′]difluorene core - a donor-acceptor multi-redox system

AU - Granhøj, Jeppe

AU - Pedersen, Viktor Bliksted Roug

AU - Mikkelsen, Kurt V.

AU - Nielsen, Mogens Brøndsted

PY - 2024

Y1 - 2024

N2 - A novel extended tetrathiafulvalene was prepared by introducing the large pentaleno[1,2-b:4,5-b′]difluorene as a central polycyclic aromatic hydrocarbon moiety. This compound behaved as a multi-redox system that could take reversibly six redox states (−1, 0, +1, +2, +3, +4). The compound exhibited strong absorptions in the visible region with an end-absorption almost reaching to 700 nm.

AB - A novel extended tetrathiafulvalene was prepared by introducing the large pentaleno[1,2-b:4,5-b′]difluorene as a central polycyclic aromatic hydrocarbon moiety. This compound behaved as a multi-redox system that could take reversibly six redox states (−1, 0, +1, +2, +3, +4). The compound exhibited strong absorptions in the visible region with an end-absorption almost reaching to 700 nm.

U2 - 10.1039/d4ob01755b

DO - 10.1039/d4ob01755b

M3 - Journal article

C2 - 39564805

AN - SCOPUS:85209767498

VL - 22

SP - 9259

EP - 9265

JO - Organic & Biomolecular Chemistry

JF - Organic & Biomolecular Chemistry

SN - 1470-4358

IS - 47

ER -