Abstract
Stereocomplexation between enantiomeric poly(L-lactide) (PLLA) and poly(D-lactide) (PDLA) is a promising sustainable approach and gaining momentum to overcome the shortcomings of polylactide (PLA) for its use as a replacement for fossil-based plastics. Filler addition in tailoring the crystallization of stereocomplex PLA (SCPLA) has attracted extensive attention; however, research has primarily focused on the heterogeneous nucleation effect of filler. The impact of filler on the chain behavior of SC-PLA during crystallization has not been exclusively discussed, and the rigid amorphous fraction (RAF) development remains unknown. In this study, the crystallization of PLLA/PDLA blends was modified by low loading of layered double hydroxide (LDH) (
Original language | English |
---|---|
Journal | International Journal of Biological Macromolecules |
Volume | 222 |
Pages (from-to) | 1101-1109 |
Number of pages | 9 |
ISSN | 0141-8130 |
DOIs | |
Publication status | Published - 2022 |
Keywords
- 2D nanoparticle
- Polymer nanocomposites
- RAF
- Nucleation
- Thermal fluctuation
- ENANTIOMERIC POLY(LACTIC ACID)S
- CRYSTAL NUCLEATION
- POLYMER LAYER
- BLENDS
- MORPHOLOGY
- POLY(L-LACTIDE)
- NANOPARTICLES
- TRANSITION
- BEHAVIOR
- SURFACE