Synthesis of bradyrhizose oligosaccharides relevant to the Bradyrhizobium O-antigen

Wei Li; Alba Silipo; Lotte Bettina Andersen Gersby; Mari-Anne Newman; Antonio Molinaro; Biao Yu

doi:10.1002/anie.201610680

Synthesis of bradyrhizose oligosaccharides relevant to the Bradyrhizobium O-antigen

Wei Li, Alba Silipo, Lotte Bettina Andersen Gersby, Mari-Anne Newman, Antonio Molinaro, Biao Yu

Section for Transport Biology

Research output: Contribution to journal › Journal article › Research › peer-review

25 Citations (Scopus)

Abstract

The unique α-(1→7)-bradyrhizoside linkages are constructed for the first time via judicious choice of the glycosylation partners and conditions, thus tetra- and penta-bradyrhizosides relevant to the peculiar O-antigen of Bradyrhizobium are synthesized, which are shown to adopt the defined right-handed helical conformations and to be unable to induce innate immune responses in plants.

Original language	English
Journal	Angewandte Chemie International Edition
Volume	56
Issue number	8
Pages (from-to)	2092-2096
Number of pages	5
ISSN	1433-7851
DOIs	https://doi.org/10.1002/anie.201610680
Publication status	Published - 2017

Keywords

Journal Article

Access to Document

10.1002/anie.201610680

Cite this

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title = "Synthesis of bradyrhizose oligosaccharides relevant to the Bradyrhizobium O-antigen",

abstract = "The unique α-(1→7)-bradyrhizoside linkages are constructed for the first time via judicious choice of the glycosylation partners and conditions, thus tetra- and penta-bradyrhizosides relevant to the peculiar O-antigen of Bradyrhizobium are synthesized, which are shown to adopt the defined right-handed helical conformations and to be unable to induce innate immune responses in plants.",

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AU - Li, Wei

AU - Silipo, Alba

AU - Gersby, Lotte Bettina Andersen

AU - Newman, Mari-Anne

AU - Molinaro, Antonio

AU - Yu, Biao

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AB - The unique α-(1→7)-bradyrhizoside linkages are constructed for the first time via judicious choice of the glycosylation partners and conditions, thus tetra- and penta-bradyrhizosides relevant to the peculiar O-antigen of Bradyrhizobium are synthesized, which are shown to adopt the defined right-handed helical conformations and to be unable to induce innate immune responses in plants.

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DO - 10.1002/anie.201610680

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